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Biodiesel is a widely used biofuel in diesel engines, which is of particular interest as a renewable fuel because it possesses the similar properties as the diesel fuel. The pure soybean biodiesel was tested in an optical constant volume combustion chamber using natural flame luminosity and forward illumination light extinction (FILE) methods to explore the combustion process and soot distribution at various ambient temperatures (800 K and 1000 K) and oxygen concentrations (21%, 16%, 10.5%). Results indicated that, with a lower ambient temperature, the autoignition delay became longer for all three oxygen concentrations and more ambient air was entrained by spray jet and more fuel was burnt by premixed combustion. With less ambient oxygen concentration, the heat release rate showed not only a longer ignition delay but also longer combustion duration.

The influence of different combustion chamber configuration, intake temperature, and coolant temperature on HCCI combustion processes were investigated in a single-cylinder optical engine. Two-dimensional images of the chemiluminescence were captured using an intensified CCD camera in order to understand the spatial distribution of the combustion. N-heptane was used as the test fuel. Three combustion chamber geometries with different squish lip, salient, orthogonal, reentrant shape, referred as V-type, H-type, and A-type respectively, were used in this study. Intake temperature was set to 65°C and 95°C, while coolant temperature was set to 85°C. The experimental data consisting of the in-cylinder pressure, heat release rate, chemiluminescence images all indicated that the different combustion chamber geometries result in different turbulence intensity in the combustion chamber, and thus affect the auto-ignition timing, chemiluminescence intensity, and combustion processes.

This paper describes numerical simulations that compare the performance of two combustion CFD models against experimental data, and evaluates the effects of combustion and spray model constants on the predicted combustion and emissions under various operating conditions. The combustion models include a Characteristic Time Combustion (CTC) model and CHEMKIN with reduced chemistry models integrated in the KIVA-3Vr2 CFD code. The diesel spray process was modeled using an updated version of the KH-RT spray model that features a gas jet submodel to help reduce numerical grid dependencies, and the effects of both the spray and combustion model constants on combustion and emissions were evaluated. In addition, the performance of two soot models was compared, namely a two-step soot model, and a more detailed model that considers soot formation from PAH precursors.

Comparisons have been made between dual-fuel (80% port-injection gasoline and 20% direct-injection diesel by mass) Highly Premixed Charge Combustion (HPCC) and blended-fuel (80% gasoline and 20% diesel) Low Temperature Combustion (LTC) modes on a 1-L single-cylinder test engine. In the HPCC mode, both early-injection (E-HPCC) and late-injection (L-HPCC) of diesel have been used. The comparisons have been conducted with a fixed fuel injection rate of 50 mg/cycle at 1500 rpm, and with the combustion phasing fixed (by adjusting the injection timing) so that the 50% heat release point (CA50) is at 8° ATDC. The rapid heat release process of LTC leads to the highest maximum pressure rise rate (MPRR). A two-peak heat release process is observed in L-HPCC, resulting in a lower MPRR. The heat release rate and MPRR values for the E-HPCC are comparable to the L-HPCC values. The EHPCC mode provides the lowest NOX emission. The soot emissions for all three modes are low.

In order to achieve high efficiency and clean combustion indiesel engines, many advanced combustion concepts have been developed to simultaneously reduce NOx and soot emissions with high efficiency. However, the benefits of these combustion modes are limited to low loads because the energy release ratesaretoo fast at high loads. Recently, Dual-fuel highly premixed charge combustion (HPCC) strategies with the port injection of gasoline and direct injection of diesel have demonstrated advantages in terms of extending the operating range by the flexible control of fuel chemical reactivity and charge stratification. However, the extension to high-load in a turbocharged multi-cylinder diesel engine with the HPCC is a critical challenge due to excessive pressure rise rates. Mean while it suffers from the excessive of CO/HC emissions at low loads.

This work concerns the oxidation of biodiesel surrogates in a CI engine. An experimental study has been carried out in a single-cylinder common-rail CI engine with soybean biodiesel and two biodiesel surrogates containing neat methyl decanoate and methyl decanoate/n-heptane blends. Tests have been conducted with various intake oxygen concentrations ranging from 21% to approximately 9% at intake temperatures of 25°C and 50°C. The results showed that the ignition delay and smoke emissions of neat methyl decanoate were closer to that of soybean biodiesel as compared with methyl decanoate/n-heptane blends. A reduced chemical kinetic mechanism for the oxidation of methyl decanoate has been developed and applied to model internal combustion engines. A KIVA code, coupled with the Chemkin chemistry solver, was used as the computational platforms. The effects of various intake oxygen concentrations on the in-cylinder emissions of OH and soot were discussed.

The effects of cooled EGR on combustion and emission characteristics in HCCI operation region was investigated on a single-cylinder diesel engine, which is fitted with port injection of DME and methanol. The results indicate that EGR rate can enlarge controlled HCCI operating region, but it has little effect on the maximum load of HCCI engine fuelled with DME/methanol dual-fuels. With the increase of EGR rate, the main combustion ignition timing (MCIT) delays, the main combustion duration (MCD) prolongs, and the peak cylinder pressure and the peak rate of heat release decreases. Compared with EGR, DME percentage has an opposite effect on HCCI combustion characteristics. The increase of indicated thermal efficiency is a combined effect of EGR rate and DME percentage. Both HC and CO emissions ascend with EGR rate increasing, and decrease with DME percentage increasing. In normal combustion, NOX emissions are near zero.

With a zero-dimensional detailed chemical kinetic model, a numerical study was carried out to investigate the chemical reaction phenomena encountered in the homogenous charge compression ignition process of dimethyl ether (DME) and methane dual fuel. The results show that the DME/methane dual fuel elementary reactions affect each other. The low temperature reaction (LTR) of DME is inhibited, the second molecular oxygen addition of DME is restrained, and β -scission plays a dominant role in DME oxidation. Hydrogen peroxide (H2O2) is controlled by DME oxidation and almost has no correlation with methane oxidation. The rich H2O2 concentration makes methane oxidation occurs at low initial temperature. Most of the formaldehyde (CH2O) is produced from H-abstraction of methoxy (CH3O) rather than from LTR of the DME. However, the heat release of methane oxidation promotes the hot flame reactions of DME which make the reactions with high activation energy occur.

By mixing iso-octane with octane number 100 and normal heptane with octane number 0, it was possible to obtain a PRF fuel with octane rating between 0 and 100. The influence of PRF fuel’s octane number on the combustion characteristics, performance and emissions character of homogeneous charge compression ignition (HCCI) engine was investigated. The experiments were carried out in a single cylinder direct injection diesel engine. The test results show that, with the increase of the octane number, the ignition timing delayed, the combustion rate decreased, and the cylinder pressure decreased. The HCCI combustion can be controlled and then extending the HCCI operating range by burning different octane number fuel at different engine mode, which engine burns low octane number fuel at low load mode and large octane number fuel at large load mode. There exists an optimum octane number that achieves the highest indicated thermal efficiency at different engine load.

Homogeneous charge compression ignition (HCCI) is considered as a high efficient and clean combustion technology for I.C. engines. Methanol is a potential fuel for HCCI combustion. In this research, a single cylinder diesel engine was applied to HCCI operation. Methanol and dimethyl ether (DME) were fueled to the engine by fuel injection system with an electric controlled port in dual fuel mode. The results show that the stable HCCI operation of DME/methanol can be obtained over a quite broad speed and load region. And compared with higher speeds, the load region is even wider at low engine speed. E.g., at the engine speed of 1000 r/min, the maximum indicated mean effective pressure(IMEP) can reach 0.77 MPa, while at 2000r/min it is 0.53 MPa. Both DME and methanol influence HCCI combustion strongly, and by regulating DME/methanol proportions the HCCI combustion process could be controlled effectively.

The effects of Exhaust Gas Recirculation (EGR) and octane number of PRF fuel on combustion and emission characteristics in HCCI operation were investigated. The results show that EGR could delay the ignition timing, slow down the combustion reaction rate, reduce the pressure and average temperature in cylinder and extend the operation region into large load mode. With the increase of the fuel/air equivalence ratio or the fuel octane number (ON), the effect of EGR on combustion efficiency improves. With the increase of EGR rate, the combustion efficiency decreases. The optimum indicated thermal efficiency of different octane number fuels appears in the region of high EGR rate and large fuel/air equivalence ratio, which is next to the boundary of knocking. In the region of high EGR rate, HC emissions rise up sharply as the EGR rate increases. With the increase of octane number, this tendency becomes more obvious.

The application of oxygen-enriched or oxy-fuel combustion coupled with carbon capture and storage technology has zero carbon dioxide emission potential in the boiler and gas turbine of the power plant. However, the oxygen-enriched combustion with high oxygen level has few studies in internal combustion engines. The fundamental issues and challenges of high oxygen level are the great differences in the physical properties and chemical effects compared with the combustion in air condition. As a consequence, the diesel spray combustion characteristics at high oxygen level were investigated in an optical constant volume vessel. The oxygen volume fraction of tested gas was from 21% to 70%, buffered with argon. The high-speed color camera was used to record the natural flame luminosity.

In order to achieve high-efficiency and clean combustion in HCCI engines, combustion must be controlled reasonably. A great variety of species with various reactivities can be produced through low temperature oxidation of fuels, which offers possible solutions to the problem of controlling in-cylinder mixture reactivity to accommodate changes in the operating conditions. In this work, in-cylinder combustion characteristics with low temperature reforming (LTR) were investigated in an optical engine fueled with low octane number fuel. LTR was achieved through low temperature oxidation of fuels in a reformer (flow reactor), and then LTR products (oxidation products) were fed into the engine to alter the charge reactivity. Primary Reference Fuels (blended fuel of n-heptane and iso-octane, PRFs) are often used to investigate the effects of octane number on combustion characteristics in engines.

In order to further study the effects of air and EGR dilution on the fuel economy improvement of natural gas engines under the premise of meeting EU6 legislation, a comparison between stoichiometric operation with EGR and lean burn operation with and without EGR has been conducted at 1600rpm 50% and 75% load. The conversion efficiencies of the catalysts for both NOx and CH4 emissions are assumed at 90% for lean burn operation. Experiment results indicate that under the condition of meeting both NOx and CH4 predetermined engine-out emissions limits for EU6 legislation, lean operation with a small fraction of EGR dilution enables more advanced combustion phasing compared to pure lean operation, which results in much better fuel economy, thus further improvement compared to stoichiometric operation is achieved.

An experimental study is carried out to compare the effects of high-pressure-loop, low-pressure-loop and dual-loop exhaust gas recirculation systems (HPL-EGR, LPL-EGR and DL-EGR) on the combustion characteristics, thermal efficiency and emissions of a diesel engine. The tests are conducted on a six-cylinder turbocharged heavy-duty diesel engine under various operating conditions. The low-pressure-loop portion (LPL-Portion) of DL-EGR is swept from 0% to 100% at several constant EGR rates, and the DL-EGR is optimized based on fuel efficiency. The results show that the LPL-EGR can attain the highest gross indicated thermal efficiency (ITEg) in the three EGR systems under all the tested conditions. At a middle load of 0.95 BMEP, 1660 r/min, the pumping losses of LPL-EGR lead to the lowest BTE among the EGR systems. The HPL-EGR can achieve the best brake thermal efficiency (BTE) and emissions within the EGR rate of 22.5% mainly due to the reduced pumping losses.

OH, soot and temperature distributions of wall-impinging diesel fuel spray were investigated in a high-temperature high-pressure constant volume combustion vessel. The ambient temperature (Ta) was set as 773 K, and the wall temperature (Tw) was set as 523 K, 673 K, 773 K, respectively. Three different injection pressures (Pi) of 60 MPa, 100 MPa, 160 MPa, and the ambient pressures (Pa) of 4 MPa were applied. The OH spatial distributions of wall-impinging spray were measured by the method of OH chemiluminescence imaging. Two-color pyrometry was applied to evaluate the spatial distributions of KL factor and flame temperature of wall-impinging spray. The results reveal that, OH chemiluminescence is observed in the region near the impingement point firstly. The regions of high OH chemiluminescence intensity and high KL factor appear in the location near the wall surface along the whole combustion process.

Liquefied natural gas (LNG) engine could provide both reduced operating cost and reduction of greenhouse gas (GHG) emissions. Stoichiometric operation with EGR and the three-way catalyst has become a potential approach for commercial LNG engines to meet the Euro VI emissions legislation. In the current study, numerical investigations on the knocking tendency of several combustion chambers with different geometries and corresponding performances were conducted using CONVERGE CFD code with G-equation flame propagation model coupled with a reduced natural gas chemical kinetic mechanism. The results showed that the CFD modeling approach could predict the knock phenomenon in LNG engines reasonably well under different thermodynamic and flow field conditions.

Effects of fuel physical and chemical properties on combustion and emissions were investigated on both metal and optical diesel engines. The new generation oxygenated biofuels, n-butanol and DMF (2,5-dimethylfuran) were blended into diesel fuel with 20% volume fraction and termed as Butanol20 and DMF20 respectively. The exhaust gas recirculation (EGR) rates were varied from zero to ∼60% covering both conventional and low temperature combustion. Meanwhile, the reference fuels such as n-heptane, cetane, and iso-cetane were also used to isolate the effects of different fuel properties on combustion and emissions. In addition, to clarify the effects of oxygenated structures on combustion and emissions, a fundamental partially premixed burner was also used. Results based on metal and optical diesel engines show that fuel cetane number is the dominated factor to affect the auto-ignition timing and subsequent combustion process.

Hybrid powertrain has been proven to be an effective fuel-saving technology in commercial vehicles, but many hybrid commercial vehicles still use conventional diesel engines, resulting in limited fuel savings. The main purpose of this study is to enhance the thermal efficiency of a dedicated hybrid diesel engine focusing on the characteristic operating conditions. Via fundamental thermodynamics process analysis of internal combustion engine, steel piston with high compression ratio, air system involving two-stage turbocharger(2TC) with an intercooler, and late intake valve closing(IVC) timing are proposed to improve the thermal efficiency of the engine. Experimental results show that high compression ratio and lower thermal conductivity of the combustion chamber surface lead to lower heat release rates, requiring optimization of piston profile to accelerate the mixing rate. Besides, high compression ratio also leads to higher mechanical losses.

Gasoline partially premixed combustion (PPC) is a potential combustion concept to achieve high engine efficiency as well as low NOx and soot emissions. But the in-cylinder process of PPC is not well understood. In the present study, the double injection strategy of PPC was investigated on a light-duty optical engine. The fuel/air mixing and combustion process of PPC was evaluated by fuel-tracer planar laser-induced fluorescence (PLIF) and high-speed natural luminosity imaging technique, respectively. Combustion emission spectra of typical double injection case were analyzed. The primary reference fuel, PRF70 (70% iso-octane and 30% n-heptane by volume) was chosen as the lower reactivity fuel like gasoline. Double injection strategies of different first fuel injection timing and mass ratio of the two fuel injections were comparatively studied.